Yang Guang Resin Chemical Co., Ltd

Знание

MSDS: MVAD-L Resin (Hydroxyl-Modified Vinyl Chloride/Vinyl Acetate Copolymer)

Identification

Product Name: MVAD-L Resin, Hydroxyl-Modified Vinyl Chloride/Vinyl Acetate Copolymer
Other Names: Hydroxylated Vinyl Co-polymer
Recommended Uses: Binders for inks, adhesives, coatings, plastics modification
Manufacturer: Refer to supplier label or technical sheet for local manufacturer contact details
Emergency Contact: Manufacturer emergency phone number or CHEMTREC 24-hour hotline
Product Code: MVAD-L
Revision Date: See label or safety data sheet for specifics
Use Restrictions: For industrial use only; not intended for pharmaceuticals, food, or cosmetics

Hazard Identification

GHS Classification: Not classed as hazardous under OSHA Hazard Communication Standards
Physical Hazards: May generate static discharge; combustible dust hazard in powder or dust form
Health Hazards: Dust inhalation may irritate nose, throat, or lungs; skin and eye contact may cause minor irritation
Environmental Hazards: Low acute aquatic toxicity, but improper disposal can impact waterways
Precautionary Statements: Avoid dust formation, use in ventilated areas, wear appropriate PPE
Pictograms: None required
Signal Word: None required
Hazard Phrase: May form combustible dust concentrations in air

Composition / Information on Ingredients

Chemical Name: Hydroxyl-Modified Vinyl Chloride/Vinyl Acetate Copolymer
CAS Number: 9002-86-2 (for Polyvinyl Chloride portion); 108-05-4 (for Vinyl Acetate); additional proprietary ingredients may be present
Content Range: Vinyl chloride: 85–95%; Vinyl acetate: 1–10%; Hydroxylated units: <5%
Additives: Stabilizers, plasticizers, or modifiers below 5% as required for performance
Hazardous Components: None above OSHA thresholds based on current knowledge
Impurities: Trace monomers below detection limits

First Aid Measures

Inhalation: Move individual into fresh air, rest in comfortable position, seek medical attention if symptoms continue
Skin Contact: Wash exposed skin with soap and water; remove contaminated clothing; medical advice needed for persistent irritation
Eye Contact: Rinse eyes gently with water for several minutes, lift eyelids; remove contact lenses if present, seek help if discomfort remains
Ingestion: Rinse mouth, drink water to dilute; do not induce vomiting, consult medical provider for persistent effects
Notes to Physician: Treat symptomatically, no specific antidote identified

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, foam, dry chemical, carbon dioxide
Unsuitable Extinguishing Media: Direct water stream on burning powder or dust could spread fire
Specific Hazards: Thermal decomposition releases hydrogen chloride, phosgene, carbon oxides
Protective Equipment for Firefighters: Self-contained breathing apparatus, full protective gear, avoid inhalation of smoke/fumes
Firefighting Instructions: Use water spray to cool exposed containers, approach from upwind side
Combustion Products: Hydrogen chloride gas, carbon dioxide, carbon monoxide, low amounts of phosgene possible at high temperatures

Accidental Release Measures

Personal Precautions: Eliminate ignition sources, use spark-proof tools, ventilate area, limit exposure to dust
Protective Equipment: Goggles, gloves, dust mask or respirator suitable for nuisance dust
Environmental Precautions: Prevent runoff into drains, sewers, waterways; contain spillage with appropriate barriers
Spill Cleanup Methods: Sweep up and place in suitable containers; avoid dry sweeping of large amounts, consider vacuum filters specifically for dust recovery
Decontamination: Wash down surfaces with water after collection of spilled material, dispose of rinse water properly

Handling and Storage

Handling: Use local exhaust ventilation for dust, ground all equipment to prevent static discharge, avoid eating or smoking in work area
Hygiene Practices: Wash hands and arms thoroughly after handling; avoid contact with skin, eyes, and clothing
Storage: Store MVAD-L resin in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and incompatible chemicals
Storage Conditions: Keep in original containers tightly closed, prohibit storage near strong acids, alkalis, or oxidizers
Incompatibilities: Avoid contact with strong acids, alkalis, oxidizing agents
Recommended Packaging Materials: Polyethylene-lined drums, moisture barrier bags

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established OSHA or ACGIH exposure limits for finished resin; treat as nuisance dust (10 mg/m³ total dust, 5 mg/m³ respirable)
Engineering Controls: Local exhaust ventilation, dust collection systems, explosion-proof electrical equipment
Personal Protective Equipment: Chemical goggles or safety glasses, gloves (nitrile or PVC), dust mask or respirator (N95 or better for dust), long sleeves
Respiratory Protection: If above control limits, use approved particulate respirator
Environmental Exposure Controls: Prevent release to surface waters through process containment and spill control

Physical and Chemical Properties

Appearance: White or off-white free-flowing powder or granules
Odor: Mild plastic odor
pH: Not applicable (insoluble in water)
Boiling Point: Not applicable
Melting Range: Softening point: 110–135°C
Flash Point: Not applicable as solid, decomposition above 200°C
Flammability: Not easily flammable under normal processing, dust may form explosive mixtures
Vapor Pressure: Negligible (solid at ambient temperature)
Bulk Density: 0.4–0.7 g/cm³
Solubility: Insoluble in water, soluble in ketones, esters, aromatic hydrocarbons
Partition Coefficient (n-octanol/water): Not determined
Decomposition Temperature: >200°C with release of hydrogen chloride
Evaporation Rate: Not applicable
Viscosity: Not applicable
Particle Size: Varies by grade, refer to product specification

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Thermal Decomposition: Decomposition begins above 200°C; releases hydrochloric acid gas and other irritant fumes
Reactivity: Non-reactive with water or typical neutral chemicals
Conditions to Avoid: Heat, open flames, sparks, direct sunlight, uncontrolled static discharge
Incompatible Materials: Strong oxidizing agents, strong acids or bases
Hazardous Polymerization: Does not occur
Hazardous Decomposition Products: Hydrogen chloride gas, carbon oxides, trace phosgene in extreme heat

Toxicological Information

Acute Toxicity: Low toxicity by oral, dermal, and respiratory routes; dust can produce irritation of upper airways
Skin Irritation: Prolonged or repeated exposure can cause minor mechanical irritation
Eye Irritation: Dust may irritate eyes, causing redness, tearing, discomfort
Inhalation Effects: Breathing airborne dusts and combustion products produces nose and throat discomfort, coughing
Chronic Effects: No known risk of chronic illness with normal use; residual monomer exposures within safe limits
Sensitization: Not known to cause skin or respiratory sensitization
Carcinogenicity: Finished copolymer not classed as carcinogenic by IARC, NTP, or OSHA
Mutagenicity/Teratogenicity: No evidence from polymer, but handle with care to reduce dust exposure

Ecological Information

Ecotoxicity: Product shows limited bioavailability due to low solubility; not expected to cause acute harm to aquatic organisms
Persistence and Degradability: Degrades slowly in the environment under sunlight (photo-oxidation) but otherwise persistent
Bioaccumulation Potential: Not expected to bioaccumulate due to molecular size and composition
Mobility in Soil: Material is not mobile in soil, tends to remain particulate
Other Adverse Effects: Particulate may contribute to physical litter or impact filter-feeding organisms if large quantities reach aquatic systems

Disposal Considerations

Waste Disposal Methods: Dispose of through licensed waste contractor; landfill or thermal treatment in compliance with local, regional, and national regulations
Incineration: Only at approved chemical waste incineration facilities; observe potential for HCl emissions
Recycling: Product suitable for approved industrial recycling where available
Contaminated Packaging: Clean containers may be recycled; otherwise dispose of as hazardous industrial waste
Sewage Disposal Restrictions: Do not discharge to sewers or waterways
Special Precautions: Avoid dispersal of dust into environment during disposal

Transport Information

UN Number: Not regulated as dangerous goods for transport
Proper Shipping Name: Not classified as hazardous
Hazard Class: None
Packing Group: None
Transport Hazard: Avoid creating or transporting dust in confined areas
Environmental Hazards: Not classified as marine pollutant
Special Precautions for Transport: Keep containers closed and secure, shield from weather, provide labels per local regulations

Regulatory Information

U.S. Regulations (OSHA): Not regulated as hazardous under OSHA criteria
TSCA Inventory: Components listed
SARA Title III Sec. 313: Contains no reportable quantities of regulated toxics
California Prop 65: No ingredients above reporting threshold listed
EU Regulations: No REACH SVHC present above thresholds, polymer exempt from registration
Other Local/Regional Requirements: Follow community-specific chemical handling, labeling, and transport laws
Label Requirements: Standard industrial labeling and handling instructions for resins