Yang Guang Resin Chemical Co., Ltd

Знание

Material Safety Data Sheet: MLC-14-55 Resin (Vinyl Chloride-Vinyl Acetate Copolymer)

Identification

Product Name: MLC-14-55 Resin
Chemical Family: Vinyl polymers
Synonyms: Vinyl Chloride-Vinyl Acetate Copolymer Resin
Company Name: Manufacturer contact required for more details
Product Use: Applications in coatings, adhesives, inks, plastics
Emergency Number: Local emergency services or poison control center
CAS Registry Number: 9003-22-9

Hazard Identification

GHS Classification: Not classed as hazardous under GHS for solid form
Physical Hazards: Fine dust may form explosive mixtures with air
Health Hazards: Dust inhalation can irritate respiratory tract, skin contact may cause dryness
Environmental Hazards: Pellet and dust spills near waterways may affect aquatic life
Signal Word: Warning for dust hazard
Pictograms: Dust explosion hazard pictogram
UPI Code: Not applicable
Precautionary Statement: Avoid creating or inhaling dust, keep away from open flames and heat

Composition / Information on Ingredients

Substance: Vinyl Chloride-Vinyl Acetate Copolymer
Typical Composition: 90–95% Vinyl Chloride, 5–10% Vinyl Acetate
Impurities: Residual monomers & plasticizers vary by batch
CAS Number (Vinyl Chloride): 75-01-4
CAS Number (Vinyl Acetate): 108-05-4
Hazardous Components: Vinyl Chloride is a known carcinogen, present only as trace residuals
Other Ingredients: Stabilizers, lubricants below 1% each

First Aid Measures

Inhalation: Move to fresh air. Seek medical attention if breathing feels difficult or coughing continues.
Skin Contact: Wash area thoroughly with soap and water. Remove contaminated clothing.
Eye Contact: Rinse eyes with low-pressure water for at least 15 minutes. Remove contact lenses.
Ingestion: Rinse mouth, drink water if conscious, never give anything by mouth to an unconscious person. Seek doctor if significant quantities swallowed.
Note to Physician: Treat symptomatically; provide supportive care.

Fire-Fighting Measures

Flammability: Dust might catch fire in air, bulk resin resists ignition
Suitable Extinguishing Media: Dry chemical powder, foam, CO2, water spray for cooling
Unsuitable Media: Direct water jets may scatter burning dust
Special Hazards: Toxic hydrogen chloride, phosgene and vinyl chloride fumes released in combustion
Protective Equipment: Self-contained breathing apparatus, full turnout gear for firefighters
Explosion Hazard: High dust concentrations in air risk dust explosions
Advice for Firefighters: Cool containers, keep upwind, do not allow run-off into drains

Accidental Release Measures

Personal Precautions: Remove sources of ignition, avoid inhalation of dust
Protective Equipment: Dust mask or respirator, gloves, protective clothing, goggles
Environmental Precautions: Prevent entry into drains, watercourses
Methods for Cleanup: Sweep up with anti-static equipment, avoid generating dust, collect for disposal in labelled containers
Reference to Other Sections: See exposure controls and disposal guidance

Handling and Storage

Handling: Use with adequate ventilation, minimize dust creation, handle away from heat, sparks, open flames
Technical Measures: Use grounding and bonding for containers, tools, to avoid static discharge
Storage Conditions: Store in cool, dry, well-ventilated area, in tightly closed containers
Incompatible Materials: Strong oxidizers, acids
Storage Class: General chemical storage
Special Rules: Keep away from ignition sources and moisture, segregate from foodstuffs

Exposure Controls and Personal Protection

Exposure Limits: OSHA PEL (Vinyl Chloride, monomer): 1 ppm TWA; dust: treat as nuisance dust 10 mg/m³
Engineering Controls: General and local exhaust ventilation
Personal Protection: Dust mask (NIOSH approved), goggles, gloves and protective clothing (cotton/antistatic material recommended)
Hygiene Measures: Wash hands after handling, do not eat/drink in work area, change contaminated clothing
Environmental Exposure Control: Dust filters for exhaust, prevent atmospheric release

Physical and Chemical Properties

Form: White free-flowing powder or granules
Color: White to off-white
Odor: Mild, characteristic
pH: Neutral (in solution)
Boiling Point: Not applicable (thermoplastic resin)
Melting Point/Softening Range: 130–180°C
Flash Point: Over 300°C (closed cup, resin form)
Flammability: Not readily flammable, dust may ignite
Solubility: Insoluble in water, soluble in some organic solvents
Vapor Pressure: Negligible for solid
Density: 1.25–1.40 g/cm3
Partition Coefficient (n-octanol/water): Not determined
Auto-ignition Temperature: Approx. 450°C

Stability and Reactivity

Chemical Stability: Stable in normal conditions, stable to light and air
Reactivity: Strong acids, bases, oxidizers may degrade resin
Conditions to Avoid: High temperature, open flames, electrostatic discharge
Decomposition Products: Releases hydrogen chloride, phosgene, and dioxins under fire/thermal decomposition
Polymerization: Not expected under normal use

Toxicological Information

Acute Toxicity: Low, may cause mild irritation to eyes, skin, respiratory tract
Specific Effects: Dust exposure may lead to coughing, sneezing, skin dryness with prolonged contact
Chronic Exposure: No specific evidence of harm at common workplace levels, trace monomers of vinyl chloride are carcinogenic, importance of controlling dust and monomer residuals
Sensitization: Not expected
Carcinogenicity: Copolymer itself does not pose cancer risk, but unreacted vinyl chloride monomer regulated due to carcinogenicity
Reproductive Effects: Not established for copolymer, monomer is suspected hazard
Medical Conditions Aggravated: Pre-existing respiratory conditions
Mutagenicity: No relevant data for copolymer

Ecological Information

Ecotoxicity: Not expected to be acutely toxic to aquatic life, but polymer particles can disrupt ecological balance if released in quantity
Persistence and Degradability: Not readily biodegradable, persistent in aquatic and soil environments
Bioaccumulative Potential: Not expected to bioaccumulate
Mobility in Soil: Low, tends to settle in sediment
Other Adverse Effects: Physical hazard to wildlife from pellet ingestion

Disposal Considerations

Waste Treatment Methods: Dispose of according to local, state, federal regulations
Disposal of Product: Landfill or controlled incineration; avoid discharge to environment
Disposal of Contaminated Packaging: Treat packaging as contaminated waste, offer to licensed waste disposal service
Recycling: Where possible, send for reprocessing
Additional Information: Do not incinerate in open air; toxic gases may form

Transport Information

UN Number: Not classified as dangerous goods for transport
UN Proper Shipping Name: Not regulated
Transport Hazard Class: Non-hazardous
Packing Group: Not assigned
Environmental Hazards: Avoid contamination of watercourses by spilled pellets/powder
Special Precautions: Keep containers closed, tie down to prevent spillage in transit

Regulatory Information

Labeling: Comply with SDS requirements for dust exposure, GHS workplace labeling
Regulations: OSHA, EU REACH, Canadian WHMIS: record of residual monomer, dust exposure
SARA Title III: Reportable quantities of vinyl chloride if monomer content exceeds thresholds
Inventory Status: Listed on TSCA, EINECS
Chemical Safety Assessment: Carried out for substance, information provided in compliance with local safety rules
Restrictions: No major consumer product restrictions, monitor industrial exposure to residual monomer